Dr. Ravi Yadav
Assistant Professor
- Office: 231, SBS
- raviyadav@iitbbs.ac.in
- Department of Chemistry
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Research Interests:
Lewis superacids Electromerism Structurally constrained p-block compounds Main group hydrides
| Degree | Discipline | Year | School |
|---|---|---|---|
| B.Sc. (Chemistry Hons.) | Major: Chemistry; Minor: Physics and Mathematics | 2014 | University of Delhi, New Delhi |
| M.Sc. | Chemistry | 2016 | IIT Delhi, New Delhi |
| Ph.D. | Inorganic Chemistry | 2019 | Karlsruhe Institute of Technology (KIT), Germany |
- Ravi Yadav, P. Janßen, M. Schropp, L. Greb, Calix[4]pyrrolato-germane-(thf)2: Unlocking the Anti-Van’t-Hoff-Le-Bel Reactivity of Germanium(IV) by Ligand Dissociation, J. Am. Chem. Soc., 2023, Accepted. DOI: 10.1021/jacs.3c04424.
- M. Haimerl, M. Piesch, Ravi Yadav, P. W. Roesky, M. Scheer, “Reactivity of E4 (E4 = P4, As4, AsP3) towards low-valent Al(I) and Ga(I) compounds’’ Chem. Eur. J., 2022, 29, e202202529. DOI: 10.1002/chem.202202529.
- Ravi Yadav, X. Sun, R. Köppe, M. T. Gamer, F. Weigend, and P. W. Roesky, “Stimuli responsive silylene: Electromerism induced reversible switching between mono- and bis-silylene” Angew. Chem. Int. Ed., 2022, e202211115. DOI: 10.1002/anie.202211115.
- Ravi Yadav, M. Schropp, D. Roth, L. Greb, “Calix[4]pyrrolato Stibenium: Lewis Superacidity by Antimony(III)-Antimony(V) Electromerism” Angew. Chem. Int. Ed., 2022, 61, e202207963. DOI: 10.1002/anie.202207963.
- X. Sun, A. K. Singh, Ravi Yadav, D. Jin, M. Haimerl, M. Scheer, P. W Roesky, “Triple-decker complexes incorporating three distinct deck architectures” Chem. Commun., 2022, 58, 673-676. DOI: 10.1039/D1CC06182H.
- Ravi Yadav, S. Sinhababu, R. Yadav, S. Kundu, “Base-stabilized formally zero-valent mono and diatomic molecular main group compounds” Dalton trans., 2022, 51, 2170-2202. (Review article). DOI:10.1039/D1DT03569J.
- B. Goswami, T. J Feuerstein, Ravi Yadav, S. Lebedkin, P. J Boden, S. T Steiger, G. Niedner‐Schatteburg, M. Gerhards, M. M Kappes, P. W Roesky, “Thermally activated delayed fluorescence and phosphorescence quenching in iminophosphonamide copper and zinc complexes” Chem. Eur. J., 2021, 27, 61, 15110-15119. DOI: 10.1002/chem.202101247.
- Ravi Yadav, M. Weber, A. K Singh, L. Münzfeld, J. Gramüller, R. M Gschwind, M. Scheer, P. W Roesky, “A Structural Diversity of Molecular Alkaline‐Earth‐Metal Polyphosphides: From Supramolecular Wheel to Zintl Ion” Chem Eur. J., 2021, 27, 56, 14128-14137. DOI: 10.1002/chem.202102355.
- Ravi Yadav, M. Dahlen, A. K Singh, X. Sun, M. T. Gamer, P. W Roesky, “Nonanuclear zinc-gold [Zn3Au6] heterobimetallic complexes”, Dalton trans., 2021, 50, 24, 8558-8566. DOI: 10.1039/D1DT01396C.
- N. Schwarz, X. Sun, Ravi Yadav, R. Köppe, T. Simler, P. W Roesky, “Application of the Redox‐Transmetalation Procedure to Access Divalent Lanthanide and Alkaline‐Earth NHC Complexes” Chem. Eur. J., 2021, 27, 50, 12857-12865. DOI: 10.1002/chem.202101923.
- N. Reinfandt, N. Michenfelder, C. Schoo, Ravi Yadav, S. Reichl, S. N Konchenko, A. N Unterreiner, M. Scheer, P. W Roesky, “d/f‐Polypnictides Derived by Non‐Classical Ln2+ Compounds: Synthesis, Small Molecule Activation and Optical Properties” Chem. Eur. J., 2021, 27, 29, 7862-7871. DOI: 10.1002/chem.202100605.
- B. Goswami, T. J Feuerstein, Ravi Yadav, R. Köppe, S. Lebedkin, M. M Kappes, P. W Roesky, “Enantiopure Calcium Iminophosphonamide Complexes: Synthesis, Photoluminescence, and Catalysis” Chem. Eur J., 2021, 27, 13, 4401-4411. DOI: 10.1002/chem.202004833.
- B. Goswami, Ravi Yadav, C. Schoo and P. W. Roesky, “Neutral and cationic enantiopure group 13 iminophosphonamide complexes”, Dalton Trans., 2020, 49, 675-681.DOI: 10.1039/C9DT04082J.
- Ravi Yadav, Md E. Hossain, R. P. Paramban, T. Simler, C. Schoo, J. Wang, G. B. Deacon, P. C. Junk and P. W. Roesky, “3d-4f Heterometallic Complexes by the Reduction of Transition Metal Carbonyls with Bulky LnII Amidinates” Dalton Trans., 2020, 49, 7701-7707. DOI: 10.1039/D0DT01271H.
- Ravi Yadav, B. Goswami, T. Simler, C. Schoo, S. Reichl, M. Scheer and P. W. Roesky, “A bis(germylene) functionalized metal-coordinated polyphosphide and its isomerization”, Chem. Commun., 2020, 56, 70, 10207-10210. DOI: 10.1039/D0CC03920A.
- Ravi Yadav, T. Simler, B. Goswami, C. Schoo, R. Köppe, S. Dey and P. W. Roesky, “Regioselective insertion of aluminium(I) in the cyclo-P5 ring of pentaphosphaferrocene” Angew. Chem. Int. Ed., 2020, 59, 9443–9447. DOI: 10.1002/anie.202002774.
- Ravi Yadav, T. Simler, S. Reichl, B. Goswami, C. Schoo, R. Köppe, M. Scheer and P. W. Roesky, “Highly selective substitution and insertion reactions of silylenes in a metal-coordinated polyphosphide” J. Am. Chem. Soc., 2020, 142, 3, 1190–1195. DOI: 10.1021/jacs.9b12151.
- X. Sun, T. Simler, Ravi Yadav, R. Köppe and P. W. Roesky, “A stable aromatic tetrasilacyclobutadiene dication”, J. Am. Chem. Soc., 2019, 141, 38, 14987–14990. DOI: 10.1021/jacs.9b08018.
- X. Chen, T. Simler, Ravi Yadav, M. T. Gamer, R. Köppe and P. W. Roesky, “Reaction of an arsinoamide with chloro tetrylenes: substitution and As –N bond insertion” Chem. Commun., 2019, 55, 9315-9318. DOI: 10.1039/C9CC04530A.
- Ravi Yadav, T. Simler, M. T. Gamer, R. Köppe and P. W. Roesky, “Rhenium is different: CO tetramerization induced by a divalent lanthanide complex in rhenium carbonyls” Chem. Commun., 2019, 55, 5765-5768. DOI: 10.1039/C9CC02350J.
- T. Simler, T. J. Feuerstein, Ravi Yadav, M. T. Gamer, R. Köppe and P. W. Roesky, “Access to divalent lanthanide NHC complexes by redox-transmetallation from silver and CO2 insertion reactions” Chem. Commun., 2019, 55, 222-225. DOI: 10.1039/C8CC08120D.
- M. K. Sharma, D. Singh, P. Mahawar, Ravi Yadav and S. Nagendran, “Catalytic cyanosilylation using germylene stabilized platinum(II) dicyanide” Dalton Trans., 2018, 47, 5943-5947. DOI: 10.1039/C8DT00043C.
2023- till date Assistant Professor, IIT Bhubaneswar (IITBBS), Odisha, India. 2019-2020 Postdoctoral Research Fellow, Karlsruhe Institute of Technology (KIT) . 2021-2023 Postdoctoral Research Fellow, University of Heidelberg.